Login to your Office 365 account to Access OneDrive for Business

Click on the OneDrive tile to launch OneDrive for Business using your browser

Click on the Sync Button on your OneDrive Web portal to setup the sync to your PC

Sign In to your one drive account if prompted. OneDrive Sync client will start to configure your desktop for OneDrive Sync.

When Prompted, choose the folders that you want to sync from OneDrive to your Desktop PC.

Click Next to Sync the files.

A OneDrive Folder will be visible in your desktop file explorer when the sync is completed.